AROMATIC ANTIAROMATIC NONAROMATIC PDF

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AROMATIC ANTIAROMATIC NONAROMATIC PDF

This study also shows omission behavior of some heterocyclic compounds with respect to their aromatic/anti aromatic/non aromatic nature due. Table 1: Aromatic, anti-aromatic and non-aromatic behavior of organic compounds. You can determine whether a ring system is aromatic, anti-aromatic, or non- aromatic by determining whether it meets certain conditions. To be aromatic, a.

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Valence bond theory uses Lewis diagrams to depict structure and bonding of covalent entities, such as molecules and polyatomic ions, henceforth molecules.

Aromatic | OChemPal

The Lewis diagram of many a molecule, however, is not consistent with the observed properties of the molecule. The Lewis diagram of some molecules suggests a ring bearing a fully conjugated pi-electron system, or loop of pi electrons, provided each atom in the ring is sp 2 — or sp-hybridized. As evident from the stability of pi electrons however, only some such rings actually have a loop of pi electrons.

Of the above examples, only the rings in 245and 7 have a loop of pi electrons. Resonance theory can predict the fact that the rings in 245and 7 have a loop of pi electrons. According to nonaromwtic theory, however, the rings in 13and 6 also should have a loop of pi electrons.

Resonance theory, evidently, is no more reliable a tool than Lewis diagrams to be used in predicting if a ring has a loop of pi electrons. Thus, the rings in 245and 7 are aromatic. A compound whose molecule contains one or more aromatic rings is called an aromatic compound. There are chemical and spectroscopic methods that can be used to experimentally determine whether a ring is aromatic or not.

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All aromatic rings share two structural features:.

The ring is planar. However, determining whether a ring is planar or not requires careful consideration of many factors.

Nonaromafic case in point is [10]annulene To accommodate the hydrogen atoms on C-2 and C-7 inside the ring, the ring is forced to deviate from planarity. Experimentally, however, [10]annulene exists exclusively as 10indicating that the stability gained by having a loop of pi electrons in 11 is outweighed by considerable angle strain. A compound whose molecule contains one or more antiaromatic rings is called an antiaromatic compound. The rings in 1 and 6 are antiaromatic.

Under all other conditions, it dimerizes rapidly. Experiments have shown that the ring in 1 is not a square but a rectangle, which is evidence that the ring in 1 does not have a loop of pi electrons.

How to Easily predict Aromatic & Anti-aromatic compounds? – Busting JEE Main

According to molecular orbital theory, 1 is a diradical, which is consistent with its extreme reactivity. All antiaromatic rings share two features: If the ring had a loop of pi electrons as implied by the Lewis diagram, the number of electrons in the loop would be equal to 4n, where n is zero or natiaromatic positive whole number. Large and, therefore, flexible rings whose Lewis structure suggests a loop of pi electrons containing 4n number of electrons avoid being antiaromatic by deviating from planarity.

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Experimentally, 3 is about as stable as any typical alkene, meaning 3 is not antiaromatic. There are no antiaromatic rings containing more than five atoms.

A compound whose molecule contains one of more nonaromatic rings is called a nonaromatic compound. A ring whose pi system contains a 4n number of electrons but avoids being antiaromatic by deviating from planarity is nonaromatic.

Experimentally, 3 exists in the following nonplanar conformation, antiiaromatic as the tub conformation, in which no two adjacent double bonds are on the same plane.

How to Easily predict Aromatic & Anti-aromatic compounds?

Thus, there is no loop of pi electrons in the ring in 3 ; 3 is nonaromatic. Thus, 10 is nonaromatic.

To find arlmatic a ring is aromatic, antiaromatic, nonaromatic, or none of the above, use the following flow chart. Rings whose Lewis diagram implies a loop of pi electrons can be classified into three classes: All aromatic rings share two structural features: